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- Title
Transition Metal-Free ipso-Functionalization of Arylboronic Acids and Derivatives.
- Authors
Zhu, Chen; Falck, John R.
- Abstract
Arylboronic acids and their derivatives have been widely exploited as important synthetic precursors in organic synthesis, materials science, and pharmaceutical development. In addition to numerous applications in transition metal-mediated cross-coupling reactions, transition metal-free transformations involving arylboronic acids and derivatives have recently received a surge of attention for converting the CB bond to CC, CN, CO, and many other CX bonds. Consequently, a wide range of useful compounds, e.g., phenols, anilines, nitroarenes, and haloarenes, has been readily synthesized. Amongst these efforts, many versatile reagents have been developed and a lot of practical approaches demonstrated. The research in this promising field is summarized in the current review and organized on the basis of the type of bonds being formed.
- Subjects
TRANSITION metals; AROMATIC compounds; ARYLATION; BORONIC acid derivatives; COUPLING reactions (Chemistry); PHENOLS
- Publication
Advanced Synthesis & Catalysis, 2014, Vol 356, Issue 11/12, p2395
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201400305