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- Title
Thermodynamic characteristics of phase conversion of structural isomers for volatile complex of ruthenium (III) trifluoroacetylacetonate.
- Authors
Sysoev, S. V.; Cheremisina, T. N.; Zelenina, L. N.; Tkachev, S. V.; Zherikova, K. V.; Morozova, N. B.; Kuratieva, N. V.
- Abstract
The comprehensive analysis of volatile β-diketonate compound—ruthenium(III) trifruoroacetylacetonate (Ru(tfac)3)—was carried out. By means of flow method in quasi-equilibrium conditions and static method the temperature dependencies of saturated vapor pressure have been measured over solid and liquid cis- and trans-modifications of Ru(tfac)3 and isomer mixture. The thermodynamic characteristics of sublimation, evaporation, melting, and phase conversion have been calculated for structural isomers. Also by differential-scanning calorimetry the temperature meanings and the thermodynamic characteristics of melting have been determined for individual isomers of Ru(tfac)3 and their mixtures. By XRD the structures for cis- and trans-modifications have been determined. Both structures consist of neutral molecules arranged in pseudo layers.
- Subjects
VAPOR pressure; RUTHENIUM; FLOW injection analysis; CALORIMETRY; THERMODYNAMICS education
- Publication
Journal of Thermal Analysis & Calorimetry, 2010, Vol 101, Issue 1, p41
- ISSN
1388-6150
- Publication type
Article
- DOI
10.1007/s10973-010-0859-9