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- Title
A Mixed Molecular Building Block Strategy for the Design of Nested Polyhedron Metal-Organic Frameworks.
- Authors
Tian, Dan; Chen, Qiang; Li, Yue; Zhang, Ying‐Hui; Chang, Ze; Bu, Xian‐He
- Abstract
A mixed molecular building block (MBB) strategy for the synthesis of double-walled cage-based porous metal-organic frameworks (MOFs) is presented. By means of this method, two isostructural porous MOFs built from unprecedented double-walled metal-organic octahedron were obtained by introducing two size-matching C3-symmetric molecular building blocks with different rigidities. With their unique framework structures, these MOFs provide, to the best of our knowledge, the first examples of double-walled octahedron-based MOFs.
- Subjects
POLYHEDRA; METAL-organic frameworks; GRAVITATION; MOLECULAR dynamics; CHEMICAL synthesis
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 3, p837
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201307681