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- Title
Polymeric Tubular Aromatic Amide Helices.
- Authors
Zhang, Dan‐Wei; Wang, Hui; Li, Zhan‐Ting
- Abstract
Conjugated polymers may be induced by intra- and/or intermolecular non-covalent forces to fold into helical conformations. Helices formed by aromatic amide, hydrazide, and urea polymers possess a well-organized cavity and depth, which is defined by their degree of polymerization. Driving forces may be intramolecular hydrogen bonding and/or solvophobicity, or guest induction. The resulting long helices represent a new class of unimacromolecular dynamic tubular architectures that exhibit unique properties or functions in, for example, molecular recognition, chirality transfer, and ion transporting. The recent advances are highlighted here.
- Subjects
ARAMID fibers; HELICES (Algebraic topology); FIBER bundles (Mathematics); INTRAMOLECULAR catalysis; MOLECULAR recognition
- Publication
Macromolecular Rapid Communications, 2017, Vol 38, Issue 15, pn/a
- ISSN
1022-1336
- Publication type
Article
- DOI
10.1002/marc.201700179