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- Title
Front Cover: Dinuclear Copper Complexes Triply Bridged by a Tetraphosphane, rac‐Ph<sub>2</sub>PCH<sub>2</sub>P(Ph)CH<sub>2</sub>P(Ph)CH<sub>2</sub>PPh<sub>2</sub> (Eur. J. Inorg. Chem. 37/2019).
- Authors
Tanase, Tomoaki; Otaki, Risa; Okue, Ayumi; Nakamae, Kanako; Nakajima, Takayuki
- Abstract
B The Front Cover b shows dinuclear copper(I) complexes triply bridged by a tetraphosphine I rac i -dpmppm ligand in Z-form with a series of diimino ligands, which emit rapid fluorescence from loosely coordinated diimino ligands in CH SB 2 sb Cl SB 2 sb solution and SP 3 sp MLCT phosphorescence in the solid state. The "dicopper firefly" switches the luminescence mechanisms by fluxional flipping of the diimino ligands. The "dicopper firefly" switches the luminescence mechanisms by fluxional flipping of the diimino ligands.
- Subjects
LIGANDS (Chemistry); LUMINESCENCE; PHOSPHORESCENCE
- Publication
European Journal of Inorganic Chemistry, 2019, Vol 2019, Issue 37, p3990
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201901013