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- Title
Synthesis and structure of a 2D Zn complex with mixed ligands stacked in offset ABAB manner.
- Authors
Qin, Ling; Wang, Yan-Qing; Ni, Gang
- Abstract
The title complex, {[Zn(ODIB)( bpdc)]·2DMF} was prepared under hydrothermal conditions (dimethylformamide and water) based on two ligands, namely, 1,1′-oxy-bis[3,5-diimidazolyl-benzene] (ODIB) and biphenyldicarboxylic acid (H bpdc). ODIB ligands link Zn cations to give layers in crystal. bpdc anions coordinate to Zn atoms, however, their introduction does not increase the dimension of the structure. Each layer is partially passes through the adjacent layers in the offset ABAB manner.
- Subjects
ZINC compounds; COMPLEX compounds synthesis; HYDROTHERMAL synthesis; DIMETHYLFORMAMIDE; DICARBOXYLIC acids; CRYSTAL structure; LIGANDS (Chemistry)
- Publication
Crystallography Reports, 2016, Vol 61, Issue 4, p616
- ISSN
1063-7745
- Publication type
Article
- DOI
10.1134/S1063774516040131