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- Title
Directed C−H Activation and Tandem Cross-Coupling Reactions Using Palladium Nanocatalysts with Controlled Oxidation.
- Authors
Kim, Kiseong; Jung, Younjae; Lee, Suyeon; Kim, Mijong; Shin, Dongwoo; Byun, Hyeeun; Cho, Sung June; Song, Hyunjoon; Kim, Hyunwoo
- Abstract
Controlled oxidation of palladium nanoparticles provided high-valent PdIV oxo-clusters which efficiently promote directed C−H halogenation reactions. In addition, palladium nanoparticles can undergo changes in oxidation states to provide both high-valent PdIV and low-valent Pd0 species within one system, and thus a tandem reaction of C−H halogenation and cross-coupling (C−N, C−C, and C−S bond formation) was successfully established.
- Subjects
PALLADIUM catalysts; COUPLING reactions (Chemistry); HALOGENATION; OXIDATION states; BOND formation mechanism
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 24, p7056
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201700301