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- Title
The [B<sub>3</sub>(NN)<sub>3</sub>]<sup>+</sup> and [B<sub>3</sub>(CO)<sub>3</sub>]<sup>+</sup> Complexes Featuring the Smallest π-Aromatic Species B<sub>3</sub><sup>+</sup>.
- Authors
Jin, Jiaye; Wang, Guanjun; Zhou, Mingfei; Andrada, Diego M.; Hermann, Markus; Frenking, Gernot
- Abstract
We report the spectroscopic identification of the [B3(NN)3]+ and [B3(CO)3]+ complexes, which feature the smallest π-aromatic system B3+. A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3L2]+ σ-donation.
- Subjects
CHEMICAL bonds; BORENES; LEWIS bases; CHEMICAL bond lengths; PHOTODISSOCIATION
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 6, p2118
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201509826