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- Title
Synergy improvement of dielectric properties and thermal conductivity in PVDF composites with core‐shell structured Ni@SiO2.
- Authors
Li, Ting; Zhou, Wenying; Li, Ying; Cao, Dan; Wang, Yun; Cao, Guozheng; Liu, Xiangrong; Cai, Huiwu; Dang, Zhi-Min
- Abstract
Developing a high dielectric constant (εr) polymer dielectrics with low dielectric loss and high thermal conductivity (TC) is still continuous demands for advanced electrical power systems. Herein, nickel (Ni) particles were encapsulated by silica (SiO2) via a sol–gel process using sodium silicate as a precursor, and the obtained core–shell Ni@SiO2 powders were blended into poly(vinylidene fluoride) (PVDF) to investigate the effects of SiO2 insulating layer and its thickness on dielectric properties and TC of composites. Compared with pristine Ni, the Ni@SiO2/PVDF composites exhibit a superior εr, and remarkably suppressed loss and conductivity, attributable to the SiO2 interlayer between the core Ni particles which effectively prevents them from direct contacts and significantly reduces the leakage loss. Moreover, the Ni@SiO2/PVDF composites still possess a high TC owing to the restrained thermal interfacial resistance and enhanced interfacial compatibility between the fillers and the matrix. The developed Ni@SiO2/PVDF composites with high k and TC but low loss are potential for microelectronic industry.
- Subjects
DIELECTRIC properties; THERMAL conductivity; THERMAL properties; SOLUBLE glass; PERMITTIVITY; DIELECTRIC loss
- Publication
Journal of Materials Science: Materials in Electronics, 2021, Vol 32, Issue 4, p4076
- ISSN
0957-4522
- Publication type
Article
- DOI
10.1007/s10854-020-05149-x