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- Title
Heterogeneous additive‐free highly selective synthesis of 2,5‐bis(hydroxymethyl)furan over catalysts with ultra‐low Pt content.
- Authors
Vikanova, Kseniia V; Chernova, Marina S; Redina, Elena A; Kapustin, Gennady I; Tkachenko, Olga P; Kustov, Leonid M
- Abstract
Ultra‐low‐loaded supported Pt catalysts showed an extremely high activity in selective hydrogenation of bioavailable 5‐hydroxymethylfurfural (5‐HMF) to the corresponding diol, i.e. 2,5‐bis(hydroxymethyl)furan (BHMF); among the synthesized catalysts with a Pt content varying in the range 0.025–0.25 wt%, the most active one appeared to be the sample 0.1% Pt/CeO2–ZrO2, which allows us to obtain BHMF with a 97% yield and 100% selectivity from 5‐HMF without the use of alkali or any other additives at a temperature of 170 °C and H2 pressure of 1 MPa, with the 5‐HMF:Pt ratio higher than 1000 mol mol–1. © 2021 Society of Chemical Industry (SCI).
- Subjects
SOCIETY of Chemical Industry (Great Britain); CATALYSTS; HYDROXYMETHYL compounds; ENVIRONMENTAL chemistry; CHEMICAL industry; FURAN derivatives; HETEROGENEOUS catalysis
- Publication
Journal of Chemical Technology & Biotechnology, 2021, Vol 96, Issue 9, p2421
- ISSN
0268-2575
- Publication type
Article
- DOI
10.1002/jctb.6785