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- Title
Enantiotopic Discrimination by Coordination‐Desymmetrized meso‐Ligands.
- Authors
Li, Yutang; Lidskog, Anna; Armengol‐Relats, Helena; Pham, Thanh Huong; Favraud, Antoine; Nicolas, Maxime; Dawaigher, Sami; Xiao, Zeyun; Ma, Dayou; Lindbäck, Emil; Strand, Daniel; Wärnmark, Kenneth
- Abstract
The first examples of enantiopure catalysts that are chiral merely due to coordination of different metal ions at enantiotopic positions of an achiral meso‐ligand are reported. These catalysts exhibit a pseudo‐Cs symmetry and are able to catalyze reactions demanding simultaneous involvement of two catalytic sites. The latter was demonstrated by application in the asymmetric ring‐opening of meso‐epoxides.
- Subjects
CATALYSTS; SYMMETRY
- Publication
ChemCatChem, 2020, Vol 12, Issue 6, p1575
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201902243