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- Title
LAYERED METAL-ORGANIC COORDINATION POLYMERS BASED ON BI- AND TRINUCLEAR CADMIUM BLOCKS AND OCTAFLUOROBIPHENYL- 4,4′-DICARBOXYLATE ANIONS.
- Authors
Cheplakova, A. M.; Gusarov, V. S.; Samsonenko, D. G.; Vinogradov, A. S.; Kovalenko, K. A.; Rakhmanova, M. I.; Fedin, V. P.
- Abstract
Two new layered metal-organic coordination polymers [Cd2(CH3CN)4(oFBPDC)2]·4CH3CN (1) and [Cd3((CH3)3СOH)4(oFBPDC)3]·3(CH3)3СOH·H2O (2), containing an octafluorobiphenyl-4,4′-dicarboxylic acid anion (oFBPDC2–) are obtained and characterized by the single crystal X-ray diffraction analysis. It is shown that on the long-term storage of 1 in air it transforms into another crystalline phase 1a. Solid 1a exhibits ultraviolet/blue photoluminescence caused by intraligand transitions.
- Subjects
COORDINATION polymers; CADMIUM; ANIONS; SINGLE crystals; X-ray diffraction; PHOTOLUMINESCENCE
- Publication
Journal of Structural Chemistry, 2022, Vol 63, Issue 6, p895
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476622060063