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- Title
Recent Advances of α-Isothiocyanato Compounds in the Catalytic Asymmetric Reaction.
- Authors
Han, Wen ‐ Yong; Zhao, Jian ‐ Qiang; Zuo, Jian; Xu, Xiao ‐ Ying; Zhang, Xiao ‐ Mei; Yuan, Wei ‐ Cheng
- Abstract
α-Isothiocyanato amides, esters and phosphonates have emerged as new types of versatile reagents for various organo- and metal-catalyzed asymmetric cascade reactions, which have attracted increasing interest of many chemists. In this review, recent advances of α-isothiocyanato compounds for the asymmetric cascade aldol/cyclization, Mannich/cyclization, Michael/cyclization, diverse [3+2] cyclization, and self-cyclization/addition reactions are summarized and classified according to the types of acceptors.
- Subjects
ASYMMETRIC synthesis; AMIDE synthesis; ORGANOCATALYSIS; ORGANIC synthesis; PHOSPHONATES; CHEMICAL reagents; ADDITION reactions
- Publication
Advanced Synthesis & Catalysis, 2015, Vol 357, Issue 14/15, p3007
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201500264