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- Title
Thermogravimetry of π–π complexes of zinc(II)tetra- tert-butylphthalocyanine with aromatic molecules.
- Authors
Lebedeva, Natalya Sh.; Parfenyuk, Elena V.
- Abstract
Physical-chemical characteristics of molecular complexes of Zn(II)tetra- tert-butylphthalocyanine (Zn( tert-Bu)4Pc) with aromatic solvents were obtained. The results show that polarization parameters of the interacting molecules play an important role in stabilization of the phthalocyanine π–π complexes. Dispersion forces are the major factor governing the π–π complex formation of Zn( tert-Bu)4Pc with aromatic molecules. The metallophthalocyanine may be applicable as efficient analytical reagent for separation of isomeric forms of aromatic molecules.
- Subjects
THERMOGRAVIMETRY; AROMATIC compounds; ORGANOMETALLIC chemistry; CHEMICAL reagents; SOLVENTS; CYANIDES
- Publication
Journal of Thermal Analysis & Calorimetry, 2007, Vol 87, Issue 2, p437
- ISSN
1388-6150
- Publication type
Article
- DOI
10.1007/s10973-006-7505-6