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- Title
The Reaction of Singlet Oxygen with 1,3-Dimethylindole in the Presence of Aldehydes. Formation of 1,2,4-Trioxanes.
- Authors
Jefford, Charles W.; Jaggi, Danielle; Boukouvalas, John; Kohmoto, Shigeo; Bernardinelli, Gérald
- Abstract
The dye-sensitized photo-oxygenation of 1,3-dimethylindole in the presence of aldehydes initially generates a zwitterionic peroxide which condenses with the carbonyl function to give the corresponding cis-fused 1,2,4-trioxanes. Acetaldehyde gives a pair of diastereomers, one of whose structures was determined by X-ray analysis ( cis, cisisomer), whereas pivaladehyde gives only the cis, cis diastereomer.
- Publication
Helvetica Chimica Acta, 1984, Vol 67, Issue 4, p1104
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19840670423