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- Title
Hypervalent Iodine(III)-Mediated Oxidative Fluorination of Alkylsilanes by Fluoride Ions.
- Authors
Xu, Peng; Wang, Feng; Fan, Guilan; Xu, Xiufang; Tang, Pingping
- Abstract
The first example of a hypervalent iodine(III)-mediated oxidative fluorination of alkylsilanes by fluoride ions without the use of transition metals is demonstrated. This reaction is operationally simple, scalable, and proceeds under mild reaction conditions. Mechanistic studies suggest the involvement of a single-electron transfer resulting from the interaction of an organopentafluorosilicate and aryliodonium difluoride, which were generated in situ from the corresponding alkylsilane and iodosobenzene, respectively, in the presence of fluoride ions.
- Subjects
ALKYLSILANES; HYPERVALENCE (Theoretical chemistry); IODINE; FLUORINATION; SINGLE electron transfer mechanisms
- Publication
Angewandte Chemie International Edition, 2017, Vol 56, Issue 4, p1101
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201609741