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- Title
Tin in silicate glasses: structure, thermodynamics and kinetics.
- Authors
Jung, Verena; Ksenofontov, Vadim; Aigner, Maria-Louisa; Pfeiffer, Thomas; Sprenger, Dirk; Felser, Claudia
- Abstract
In this work Mössbauer spectroscopy is used to investigate the oxidation states and structures of tin in silicate glasses. Thermal treatment of the glasses in atmospheres with varying oxygen partial pressure leads to the simultaneous appearance of reduction and diffusion. Experiments with varying treatment time give the opportunity to study diffusion and reduction processes in detail. Comparison of the hyperfine parameters of reference materials with measured parameter provides information about the local surroundings of the tin atoms. An octahedral surrounding for Sn4 + is presumed, while Sn2 + and three oxygen atoms form a tetrahedral coordination.
- Subjects
OXIDATION; SPECTRUM analysis; THERMODYNAMICS; DYNAMICS; SILICATE fibers
- Publication
Hyperfine Interactions, 2008, Vol 183, Issue 1-3, p215
- ISSN
0304-3843
- Publication type
Article
- DOI
10.1007/s10751-008-9755-0