We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
A Selective Rh<sup>I</sup>-Catalyzed Substrate-Controlled C−C Bond Activation of Benzyl Sulfonamide/Alcohol-Tethered Alkylidenecyclopropanes.
- Authors
Chen, Kai; Liu, Jia ‐ Xin; Tang, Xiang ‐ Ying; Shi, Min
- Abstract
Benzyl sulfonamide/alcohol-tethered alkylidenecyclopropanes undergo a rhodium-catalyzed and substrate-controlled selective C−C bond activation, producing three types of common organic structural units: benzo[c]azepine/oxepines, dihydronaphthalen-1-amines, and conjugated dienes. Epoxidation and aromatization of these products to construct two useful compounds have also been achieved.
- Subjects
SULFONAMIDES; EPOXIDATION; POLYMERIZATION; AROMATIZATION; AROMATIC compounds
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 33, p11549
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201602366