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- Title
Frontispiece: Crown-Shaped Tungstogermanates as Solvent-Controlled Dual Systems in the Formation of Vesicle-Like Assemblies.
- Authors
Artetxe, Beñat; Reinoso, Santiago; San Felices, Leire; Gutiérrez ‐ Zorrilla, Juan M.; García, José A.; Haso, Fadi; Liu, Tianbo; Vicent, Cristian
- Abstract
Polyoxometalates The reaction of early lanthanides, GeO2, and Na2WO4 in buffered medium was systematically studied and a series of hexameric and dodecameric polyoxometalates with a closely related crown ‐ shaped framework based on [Ln2GeW10O38]6 – Keggin ‐ type subunits was isolated. The dodecamers represent the first macroions with dual behavior in the formation of vesicle ‐ like structures that lead to different supramolecular assemblies in terms of composition and size by a solvent ‐ triggered skeletal modification of the species undergoing self ‐ association. For more details, see the Full Paper by S. Reinoso et al. on page 7736 ff.
- Subjects
POLYOXOMETALATES; SOLVENTS; GERMANIUM
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 21, pn/a
- ISSN
0947-6539
- Publication type
Other
- DOI
10.1002/chem.201582162