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- Title
Zinc(II) Complexes with Dangling Functional Organic Groups.
- Authors
Yang, Jingxia; Puchberger, Michael; Qian, Renzhe; Maurer, Christian; Schubert, Ulrich
- Abstract
Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional p-substituted benzene derivatives (a combination of carboxylate, oximate, amino, β-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From the reaction with p-aminobenzoic acid, the compound [Zn2(OOCCH3)(OOC-C6H4-NH2)3]∞ was crystallized. It is a three-dimensional coordination polymer with bridging aminobenzoate ligands.
- Subjects
ZINC compounds; BENZENE derivatives; ORGANIC compounds research; LIGANDS (Chemistry); CARBOXYLATES
- Publication
European Journal of Inorganic Chemistry, 2012, Vol 2012, Issue 27, p4294
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201200558