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- Title
Synthesis, Characterization and Crystal Structure of New 2-Morpholinoethyl-Substituted Bis-(NHC)Pd(II) Complexes and the Catalytic Activity in the Direct Arylation Reaction.
- Authors
Sarı, Yakup; Aktaş, Aydın; Barut Celepci, Duygu; Gök, Yetkin; Aygün, Muhittin
- Abstract
This paper contains the synthesis of the new 2-morpholinoethyl substituted bis-(NHC)Pd(II) complexes and their catalytic activity in direct arylation reaction. The new bis-(NHC)Pd(II) complexes have been prepared from Ag(I)NHC complexes by using transmetallation method. The new bis-(NHC)Pd(II) complexes have been characterized by using H NMR, C NMR, FTIR spectroscopy and elemental analysis techniques. Molecular and crystal structure of the complex 1a and its ligand ( N-benzylbenzimidazole) were obtained by single crystal X-ray diffraction method. The new bis-(NHC)Pd(II) complexes exhibit activity in the reaction after being examined as catalysts in the direct arylation (C-H activation) reaction. Graphical Abstract:
- Subjects
COMPLEX compounds synthesis; METAL complexes; PALLADIUM compounds; CRYSTAL structure; CATALYTIC activity; ARYLATION
- Publication
Catalysis Letters, 2017, Vol 147, Issue 9, p2340
- ISSN
1011-372X
- Publication type
Article
- DOI
10.1007/s10562-017-2132-3