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- Title
Photochemical C−H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot.
- Authors
Hernández‐Guerra, Daniel; Hlavačková, Anna; Pramthaisong, Chiranan; Vespoli, Ilaria; Pohl, Radek; Slanina, Tomáš; Jahn, Ullrich
- Abstract
A mild, atom‐economic, and metal‐free α‐C−H amination of ethers using relatively stable nonafluorobutanesulfonyl (nonaflyl, Nf) azide as the aminating reagent to give N‐sulfonyl hemiaminals is reported. This enables unprecedented C(sp3) difunctionalization reactions, leading to diverse functionalized amino group containing compounds starting from simple ethers in one pot.
- Subjects
AMINATION; ETHERS; AMINO group; HEMIAMINALS; POTS; SULFONYL compounds
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 36, p12570
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201905209