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- Title
Iron‐Catalyzed Carbenoid‐Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study.
- Authors
Vaitla, Janakiram; Bayer, Annette; Hopmann, Kathrin H.
- Abstract
A method for the generation of unprecedented vinyl carbenoids from sulfoxonium ylides has been developed and applied in the synthesis of a diverse array of heterocycles such as indolizines, pyrroles, 3‐pyrrolin‐2‐ones, and furans. The reactions proceed by FeBr2 catalysis under mild reaction conditions with a broad substrate scope. A reaction pathway involving iron carbenoids is proposed based on a series of control experiments and DFT calculations.
- Subjects
DENSITY functional theory; FURANS; HETEROCYCLIC compounds; YLIDES; CATALYSIS
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 49, p16412
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201810451