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- Title
Direct Synthesis of Silylamine from N<sub>2</sub> and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.
- Authors
Liao, Qian; Cavaillé, Anthony; Saffon ‐ Merceron, Nathalie; Mézailles, Nicolas
- Abstract
A homogeneous system which is able to yield silylamine from N2 and bis(silane) in one pot is reported. Mechanistically a {(triphosphine)molybdenum(I)} fragment, generated in situ, splits N2 into the corresponding nitrido complex at room temperature. Then, functionalization of the molybdenum nitrido is achieved by double Si−H addition under mild reaction conditions. Moreover, the bis(silyl)amine product is decoordinated from the metal center.
- Subjects
SILANE; MOLYBDENUM; PHOSPHINE; AMINE derivatives; CHEMICAL reactions
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 37, p11378
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201604812