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- Title
Tailor-Made Ruthenium-Triphos Catalysts for the Selective Homogeneous Hydrogenation of Lactams.
- Authors
Meuresch, Markus; Westhues, Stefan; Leitner, Walter; Klankermayer, Jürgen
- Abstract
The development of a tailored tridentate ligand enabled the synthesis of a molecular ruthenium-triphos catalyst, eliminating dimerization as the major deactivation pathway. The novel catalyst design showed strongly increased performance and facilitated the hydrogenation of highly challenging lactam substrates with unprecedented activity and selectivity.
- Subjects
RUTHENIUM catalysts; LACTAMS; CHEMICAL synthesis; CATALYTIC hydrogenation; DIMERIZATION; SUBSTRATES (Materials science)
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 4, p1414
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201509650