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- Title
Dry Reforming of Methane (DRM) by Highly Active and Stable Ni Nanoparticles on Renewable Porous Carbons.
- Authors
Li, Yinming; Wang, Zhaojia; Zhang, Bo; Liu, Zhengang; Yang, Tianxue
- Abstract
In this study, Ni nanoparticles supported on renewable porous carbon were prepared using hydrochar as a carbon precursor via in situ formation and self-reduction. The structure properties of the prepared nanocatalysts were characterized by multiple techniques, including XRD, SEM, and HR-TEM, and the dry reforming of methane (DRM) performance of the nanocatalysts in terms of conversion efficiency and reactivity stability was evaluated. The results revealed that the Ni2+ was uniformly anchored on the surface of the hydrochar, and subsequently the Ni nanoparticles were well dispersed in the composite with a diameter of less than 8 nm and had a narrow particle size distribution at a temperature lower than 800 °C. With an increased temperature from 800 to 900 °C, the significant sintering and agglomeration of nickel particles and the transformation from amorphous carbon to graphitic structure were observed in the composite. The nanocatalysts prepared at a temperature of 700 °C (Ni@C-700) and 800 °C (Ni@C-800) exhibited a high reforming conversion rate and catalytic stability of CH4 by CO2 (around 52% for Ni@C-700 and 70% for Ni@C-800 after 800 min of run-time, respectively). As for the composite obtained at 900 (Ni@C-900), the highly graphitic degree was coupled with the significantly increased nickel particle size, and this resulted in a remarkably decreased conversion efficiency. The present study offers a valuable application of the hydrochar and a facile and green approach to prepare highly active and cost-efficient Ni nanoparticles on porous carbons towards the dry reforming of methane.
- Subjects
PARTICLE size distribution; NANOPARTICLES; METHANE; AMORPHOUS carbon; CARBON foams; TEMPERATURE distribution; METAL nanoparticles
- Publication
Catalysts (2073-4344), 2020, Vol 10, Issue 5, p501
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal10050501