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- Title
Selective Catalytic Transfer Hydrogenolysis of Glycerol to 2-Isopropoxy-Propan-1-Ol over Noble Metal Ion-Exchanged Mordenite Zeolite.
- Authors
Singh, Bhupendra Kumar; Kim, Yongseok; Kwon, Seungdon; Na, Kyungsu
- Abstract
This study investigated the selective conversion of glycerol to 2-isopropoxy-propan-1-ol over noble metal ion-exchanged mordenite zeolites (RuMOR, RhMOR, and PdMOR) as heterogeneous catalysts via catalytic transfer hydrogenolysis (CTH) using propan-2-ol as the solvent, hydrogen supplier, and reactive coupling reagent with glycerol. The catalytic reactions were performed at 140 °C under inert conditions with a 0.5 MPa initial pressure of N2. A single product, 2-isopropoxy-propan-1-ol, was catalytically generated without any appreciable by-products. The catalytic results were reproducible, and the catalysts exhibited good recyclability.
- Subjects
PRECIOUS metals; MORDENITE; HYDROGENOLYSIS; GLYCERIN; HETEROGENEOUS catalysts; ZEOLITES
- Publication
Catalysts (2073-4344), 2019, Vol 9, Issue 11, p885
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal9110885