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- Title
Molecular Oxygen Modulated Luminescence of an Octahedro-hexamolybdenum Iodide Cluster having Six Apical Thiocyanate Ligands.
- Authors
Riehl, Lara; Ströbele, Markus; Enseling, David; Jüstel, Thomas; Meyer, H.‐Jürgen
- Abstract
The synthesis, characterization, and luminescence properties of (Bu4N)2[Mo6I8(NCS)6] are reported. Orange crystals of (Bu4N)2-[Mo6I8(NCS)6] were crystallized from acetone solution and used for X-ray single-crystal structure determination and refinement, yielding a structure with a centrosymmetric [Mo6I8(NCS)6]2- ion. Photoluminescence studies on the crystalline solid revealed a broad excitation in the UV/Vis region and an emission around 690 nm. The red emission intensity decreases with increasing partial pressure of atmospheric molecular O2.
- Subjects
MOLYBDENUM compounds synthesis; THIOCYANATES; IODIDES; LUMINESCENCE; ATMOSPHERIC oxygen; CRYSTAL structure; LIGANDS (Chemistry)
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2016, Vol 642, Issue 5, p403
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201600021