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- Title
A fluorescence study of the solute-solvent interactions of aminochalcones in a room-temperature ionic liquid.
- Authors
Santhosh, Kotni; Grandhi, G. Krishnamurthy; Ghosh, Snigdha; Samanta, Anunay
- Abstract
Unlike most other electron donor-acceptor (EDA) molecules, aminochalcones exhibit unusual solvent polarity-dependent fluorescence behavior. The photophysical behavior of two aminochalcones, namely, 4-aminochalcone (AC) and 4-dimethylaminochalcone (DMAC), has been studied in a viscous room-temperature ionic liquid (IL), 1-butyl-3- methylimidazolium hexafluorophosphate, [bmim][PF6], by steady-state and time-resolved fluorescence techniques. The observation of a single emission band in viscous IL, which is similar to the one observed in less viscous polar conventional solvents, suggests no twisting is necessary for the formation of the charge-transfer state from which the emission of aminochalcones originates. The fluorescence decay profiles, solvation dynamics, and excitation- wavelength-dependent emission behavior of AC are found to be quite different from those of DMAC in the IL. The observed difference is attributed to specific H-bonding interaction between AC and [bmim][PF6].
- Subjects
FLUORIMETRY; CHALCONES; IONIC liquids; ELECTRON donor-acceptor complexes; POLAR solvents; PHOSPHATES; CHARGE transfer
- Publication
Pure & Applied Chemistry, 2013, Vol 85, Issue 7, p1451
- ISSN
0033-4545
- Publication type
Article
- DOI
10.1351/PAC-CON-12-10-28