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- Title
Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses.
- Authors
Martinand-Lurin, Elodie; Dos Santos, Aurélie; Robineau, Emmanuelle; Retailleau, Pascal; Dauban, Philippe; Grimaud, Laurence; Kaïm, Laurent El
- Abstract
Initial conditions disclosed for the Passerini-Smiles reaction are associated with a lack of efficiency that has prevented chemists from using it since its discovery. We wish to report herein our thorough study in the development of new experimental conditions for this coupling between electron-poor phenols, isocyanides, and carbonyl derivatives. These new conditions have been applied to several synthetic strategies towards benzoxazinones.
- Publication
Molecules, 2016, Vol 21, Issue 9, p1257
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules21091257