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- Title
Organocatalysis in Enantioselective α-Functionalization of 2-Cyanoacetates.
- Authors
Díaz ‐ de ‐ Villegas, María D.; Gálvez, José A.; Badorrey, Ramón; López ‐ Ram ‐ de ‐ Víu, Pilar
- Abstract
Recent progress in asymmetric organocatalysis has led to the development of several asymmetric transformations that employ various substrates. Among these, cyanoacetates have emerged as excellent nucleophiles in conjugate addition, alkylation, Mannich and α-heterofunctionalization reactions. In this review we discuss the enantioselective functionalization of 2-cyanoacetates through organocatalytic reactions.
- Subjects
ORGANOCATALYSIS; ENANTIOSELECTIVE catalysis; ASYMMETRIC synthesis; NUCLEOPHILES; CYANIDES; BIOCHEMICAL substrates; CATALYSIS
- Publication
Advanced Synthesis & Catalysis, 2014, Vol 356, Issue 16, p3261
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201400404