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- Title
One-Bond <sup>13</sup>C, <sup>13</sup>C-Spin Coupling in η<sup>4</sup>-, η<sup>3</sup>- and η<sup>2</sup>-Olefin Transition Metal Complexes.
- Authors
Zobl-Ruh, Susanne; von Philipsborn, Wolfgang
- Abstract
One-bond 13C, 13C-spin-coupling constants have been measured, with natural isotope abundance, in η4-diene, η3-allyl and η2-ene transition-metal carbonyl complexes. Typical values of 1 J(C,C) are given for Fe-, Ru- and Os-complexes with the three types of olefinic ligands. The effects of substituents and the structural significance of the C,C-coupling constants are discussed.
- Publication
Helvetica Chimica Acta, 1981, Vol 64, Issue 7, p2378
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19810640744