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- Title
A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity.
- Authors
Neniškis, Algirdas; Račkauskaitė, Dovilė; Shi, Qixun; Robertson, Aiden J.; Marsh, Andrew; Ulčinas, Artūras; Valiokas, Ramūnas; Brown, Steven P.; Wärnmark, Kenneth; Orentas, Edvinas
- Abstract
Abstract: A new strategy towards tubular hydrogen‐bonded polymers based on the self‐assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1H fast magic‐angle spinning (MAS) solid‐state NMR. The molecular tubes obtained possess large internal diameter and tailor‐made outer functionalities rendering them potential candidates for a number of applications.
- Subjects
HYDROGEN bonding; SUPRAMOLECULAR polymers; TAUTOMERISM; SOLID state chemistry; NUCLEAR magnetic resonance
- Publication
Chemistry - A European Journal, 2018, Vol 24, Issue 53, p14028
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201803701