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- Title
Phosphine/Sulfoxide‐Supported Carbon(0) Complex.
- Authors
Lozano González, Mariana; Bousquet, Laura; Hameury, Sophie; Alvarez Toledano, Cecilio; Saffon‐Merceron, Nathalie; Branchadell, Vicenç; Maerten, Eddy; Baceiredo, Antoine
- Abstract
Abstract: A new carbon(0) complex <bold>2</bold> with two different L ligands, a phosphine and a sulfoxide, was synthesized and fully characterized. This new type of carbone exhibits excellent coordination ability, in contrast to the related phosphine/sulfide‐supported carbon(0) complexes. Several organometallic complexes were isolated and, of special interest, the νav(CO) value of RhI‐dicarbonyl complex indicates that <bold>2</bold> has a donor capability superior to classical NHCs.
- Subjects
PHOSPHINE; SULFOXIDES; CARBON compounds; LIGANDS (Chemistry); ORGANOMETALLIC compounds
- Publication
Chemistry - A European Journal, 2018, Vol 24, Issue 11, p2570
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201705557