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- Title
Kinetics of the early stages of oct-1-ene and cyclooctene oxidation with molecular oxygen in the presence of MoS<sub>2</sub>.
- Authors
Trach, Yu.; Bulgakova, L.; Makota, O.; Schulze, B.
- Abstract
The kinetics of the early stages of the liquid-phase oxidation of oct-1-ene and cyclooctene with molecular oxygen in the presence of MoS2 and tert-butyl hydroperoxide is reported. MoS2 initiates oct-1-ene oxidation and inhibits cyclooctene oxidation. This is explained by the different reactivities of the hydroperoxide-containing complexes in the radical generation reaction. A kinetic scheme is suggested, and kinetic parameters of the process are calculated.
- Subjects
MOLECULAR dynamics; HYDROGEN peroxide; OXIDATION; PHOTOSYNTHETIC oxygen evolution; OXYGEN
- Publication
Kinetics & Catalysis, 2008, Vol 49, Issue 2, p231
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158408020109