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- Title
Dehydrogenation of 1-aryl(hetaryl)-1,2,3,4-tetrahydro-9 H-β-carboline-3-carboxylic acids and their esters with dimethyl sulfoxide.
- Authors
Abramyants, M.; Lomov, D.; Zavyazkina, T.
- Abstract
Oxidative dehydrogenation of 1-aryl(hetaryl)-1,2,3,4-tetrahydro-9 Н-β-carboline-3-carboxylic acids derivatives with dimethyl sulfoxide leads to the formation of 1-aryl(hetaryl)-9 Н-β-carbolines. Simultaneously with the dehydrogenation decarboxylation occurs. At the oxidation with dimethyl sulfoxide of methyl 1-aryl (hetaryl)-1,2,3,4-tetrahydro-9 Н-β-carboline-3-carboxylicates methyl 1-aryl(hetaryl)-9 Н-β-carboline-3-carboxylates formed whose hydrolysis afforded the corresponding 1-aryl(hetaryl)-9 Н-β-carboline-3-carboxylic acids.
- Subjects
CARBOXYLIC acids; DIMETHYL sulfoxide; CARBOLINES; DEHYDROGENATION; ESTER derivatives; DECARBOXYLATION; HYDROLYSIS; ARYLATION
- Publication
Russian Journal of Organic Chemistry, 2016, Vol 52, Issue 11, p1610
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428016110117