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- Title
M<sub>m</sub>H<sub> n</sub>( XO<sub>4</sub>)<sub>( m + n)/2</sub> crystals: structure, phase transitions, hydrogen bonds, conductivity. II. Structure and properties of Cs<sub>3</sub>(HSO<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>PO<sub>4</sub>) and Cs<sub>4</sub>(HSO<sub>4</sub>)<sub>3</sub>(H<sub>2</sub>PO<sub>4</sub>) single crystals
- Authors
Makarova, Irina; Grebenev, Vadim; Dmitricheva, Elena; Vasiliev, Ilya; Komornikov, Vladimir; Dolbinina, Valentina; Mikheykin, Alexey
- Abstract
Cs3(HSO4)2(H2PO4) and Cs4(HSO4)3(H2PO4) single crystals were obtained for the first time based on a systematic study of the phase diagram of the CsHSO4-CsH2PO4-H2O ternary system. To reveal the structural conditionality for anomalies in physical properties, including dielectric and optical properties, diffraction studies of the crystal structure of Cs3(HSO4)2(H2PO4) and Cs4(HSO4)3(H2PO4) were performed, and their common structural features and differences were analyzed.
- Subjects
HIGH temperatures; HYDROGEN bonding; SINGLE crystals
- Publication
Acta Crystallographica Section B: Structural Science, Crystal Engineering & Materials, 2016, Vol 72, Issue 1, p133
- ISSN
2052-5192
- Publication type
Article
- DOI
10.1107/S2052520615023069