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- Title
Ruthenium-Catalyzed Intramolecular Allylic Dearomatization/Migration Reaction of Indoles and Pyrroles.
- Authors
Yang, Ze ‐ Peng; Zhuo, Chun ‐ Xiang; You, Shu ‐ Li
- Abstract
An efficient synthesis of polycyclic indole and pyrrole derivatives via a ruthenium-catalyzed intramolecular allylic dearomatization/migration reaction has been developed. This method features wide substrate scope, mild reaction conditions, and an operationally simple procedure. The capture of the spiro intermediate provides solid evidence for the dearomatization/migration reaction pathway.
- Subjects
CHEMICAL synthesis; INDOLE compounds; PYRROLE derivatives; RUTHENIUM; MIGRATION reactions (Chemistry)
- Publication
Advanced Synthesis & Catalysis, 2014, Vol 356, Issue 8, p1731
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201301083