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- Title
1-Bromoindene — A new synthon for the preparation of (indenyl)Ni(II)(PPh<sub>3</sub>)Br.
- Authors
Boucher, Sylvain; Zargarian, Davit
- Abstract
The oxidative addition of the carbon–bromine bond in 1-bromoindene to Ni(PPh3)4 gives the complex (indenyl)Ni(PPh3)Br (1) in 95% yield. In contrast, other nickel(0) species such as Ni(PMe3)4 and Ni(COD)2 promote the oxidative coupling of 1-bromoindene to 1,1′-biindene. Complex 1 has been characterized by NMR spectroscopy (1H, 13C, 31P) and single-crystal X-ray structural analysis.
- Subjects
OXIDATIVE stress; CARBON compounds; NUCLEAR magnetic resonance spectroscopy; X-ray crystallography; NICKEL
- Publication
Canadian Journal of Chemistry, 2006, Vol 84, Issue 2, p233
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/V05-248