We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
β-Elimination in 1,1,1-Trichloro-2,2-bis(4-nitrophenyl)ethane by the Action of Sodium Nitrite in Dipolar Aprotic Solvents.
- Authors
Guzov, E. A.; Kazin, V. N.; Zhukova, A. A.
- Abstract
The kinetics of dehydrochlorination of 1,1,1-trichloro-2,2-bis(4-nitrophenyl)ethane with sodium nitrite in dipolar aprotic solvents have been studied. Quantum chemical simulation of the process has been performed, and its thermodynamic parameters have been determined. The effects of dissociation and solvation on the rate constant have been considered. The reaction mechanism has been identified as E2H.
- Subjects
NITROPHENYL compounds; DIPOLAR aprotic solvents; REACTION mechanisms (Chemistry); QUANTUM chemistry; DISSOCIATION (Chemistry)
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 10, p2044
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218100031