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- Title
Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides.
- Authors
Kovrugin, Vadim M.; Colmont, Marie; Siidra, Oleg I.; Charkin, Dmitry O.; Aliev, Almaz; Krivovichev, Sergey V.; Mentré, Olivier
- Abstract
Single crystals of new Mn2[Bi2O](SeO3)4 (I), MnBi(SeO3)2Cl (II), MnIIMnIII(SeO3)2Cl (III), Mn5(SeO3)2Cl6 (IV), and Mn4(Mn5,Bi)(SeO3)8Cl5 (V) have been synthesized by chemical vapour transport and hydrothermal methods. They have been structurally characterized by single crystal X-ray diffraction analysis. The compounds II–V are the first Mn selenite chlorides, while the I, II and V compounds are the first Bi-containing Mn oxoselenites. Structural relationships of the new phases with other compounds are discussed. An overview of the mixed-ligand MnOmCln polyhedra in inorganic compounds is given.
- Subjects
MANGANESE; SELENITES; X-ray diffraction; LIGANDS (Chemistry); INORGANIC compounds
- Publication
Zeitschrift für Kristallographie. Crystalline Materials, 2019, Vol 234, Issue 3, p141
- ISSN
2194-4946
- Publication type
Article
- DOI
10.1515/zkri-2018-2088