We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Towards Unveiling the Exact Molecular Structure of Amorphous Red Phosphorus by Single‐Molecule Studies.
- Authors
Zhang, Song; Qian, Hu‐jun; Liu, Zhonghua; Ju, Hongyu; Lu, Zhong‐yuan; Zhang, Haiming; Chi, Lifeng; Cui, Shuxun
- Abstract
Since the discovery of amorphous red phosphorus (a‐red P) in 1847, many possible structures have been proposed. However, the exact molecular structure has not yet been determined because of its amorphous nature. Herein several methods are used to investigate basic properties of a‐red P. Data from scanning tunneling microscopy (STM) and gel permeation chromatography (GPC) confirm that a‐red P is a linear inorganic polymer with a broad molecular weight distribution. The theoretical single‐molecule elasticities of the possible a‐red P structures are obtained by quantum mechanical (QM) calculations. The experimental single‐molecule elasticity of a‐red P measured by single‐molecule AFM matches with the theoretical result of the zig‐zag ladder structure, indicating that a‐red P may adopt this structure. Although this conclusion needs further validation, this fundamental study represents progress towards solving the structure of a‐red P. It is expected that the strategy utilized in this work can be applied to study other inorganic polymers.
- Subjects
MOLECULAR structure; PHOSPHORUS; SINGLE molecules; SCANNING tunneling microscopy; GEL permeation chromatography
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 6, p1673
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201811152