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- Title
Design and Analysis of POM‐Guanidine Compounds: Achieving Ultra‐High Single‐Crystal Proton Conduction.
- Authors
Wang, Meng‐Meng; Cai, Jun‐Jie; Lun, Hui‐Jie; Lv, Ming‐Guang; Zhang, Jing‐Qi; Andra, Swetha; Li, Beibei; Dang, Dong‐Bin; Bai, Yan; Li, Ya‐Min
- Abstract
The "visible" proton‐conducting pathway offers a distinct advantage for researching the mechanism of proton conducting materials at the molecular level and developing new materials. To achieve this, three crystalline materials are constructed via acid–base chemistry based on phosphomolybdic acid and diversfied guanidine, namely, (CN3H6)6(PMo12O40)2·H2O (GH–PMo12), (CN4H7)3(PMo12O40)·H2O (AGH–PMo12), and (CN5H8)3(PMo12O40)·3.5H2O (DAGH–PMo12). Proton conductivity of GH–PMo12 in the [001] direction reaches up to 0.19 S cm−1 at 85 °C and 98% RH, as elucidated by impedance studies of single crystals. The clear proton transport path is proposed through the analysis of single crystal structure. Moreover, impedance studies of powder crystals reveal that the proton conductivity of GH–PMo12 is higher than that of the other two compounds. The underlying reasons for this result are clarified through the analysis of the pKa, proton density, and spatial structure. Additionally, GH–PMo12 is fabricated into composite membrane with a peak proton conductivity of 5.31 × 10−2 S cm−1, which exhibits promising potential for real‐world applications.
- Subjects
PROTON conductivity; ACID-base chemistry; SINGLE crystals; COMPOSITE membranes (Chemistry); PHOSPHOMOLYBDIC acid; GUANIDINES
- Publication
Advanced Functional Materials, 2024, Vol 34, Issue 7, p1
- ISSN
1616-301X
- Publication type
Article
- DOI
10.1002/adfm.202311912