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- Title
Nano tetraimine Pd(0) complex as an efficient catalyst for phosphine-free.
- Authors
Mandegani, Zeinab; Asadi, Mozaffar; Asadi, Zahra
- Abstract
A nano tetraimine Pd(0) complex catalyst was successfully used as an efficient heterogeneous catalyst for the phosphine-free palladium-catalysed Suzuki in water at 80 °C. This nano tetraimine Pd(0) complex was also used for copper-free in dimethylformamide at 100 °C. The catalyst was easily recovered from the reaction mixture by centrifugation and reused for at least six cycles without any significant loss in its . Analysis of the reaction mixture using analysis showed that leaching of palladium from the catalyst was negligible. The reactions can be performed efficiently for aryl iodides, bromides and also chlorides. Copyright © 2016 John Wiley & Sons, Ltd.
- Subjects
PALLADIUM catalysts; PHOSPHINE; SONOGASHIRA reaction; SUZUKI reaction; HETEROGENEOUS catalysis; DIMETHYLFORMAMIDE; NANOCOMPOSITE materials; CENTRIFUGATION
- Publication
Applied Organometallic Chemistry, 2016, Vol 30, Issue 8, p657
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.3486