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- Title
Simple Synthesis of Functionalized 2‐Phosphanaphthalenes.
- Authors
Mei, Yanbo; Wu, Dong‐Jun; Borger, Jaap E.; Grützmacher, Hansjörg
- Abstract
Abstract: A simple synthesis of sodium 2‐phosphanaphthalene‐3‐olate (<bold>1</bold>) based on the extrusion of N2 from phthalazine using Na[OCP] is reported. This heterocycle can be readily functionalized at the negatively charged oxygen center using a variety of electrophilic substrates. The coordination chemistry of both <bold>1</bold> and its neutral derivatives was explored, revealing their facile use as P‐donor ligands for late‐transition‐metal complexes.
- Subjects
NAPHTHALENE synthesis; EXTRUSION process; PHTHALAZINE; HETEROCYCLIC compounds; COORDINATE covalent bond; TRANSITION metal complexes
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 19, p5610
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201802242