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- Title
Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−.
- Authors
Ibrahim, Masooma; Baksi, Ananya; Peng, Yan; Al-Zeidaneen, Firas Khalil; Mbomekallé, Israël M.; de Oliveira, Pedro; Anson, Christopher E.
- Abstract
Reaction of the trilacunary Wells−Dawson anion {α-P2W15O56}12− with ErIII ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H2O)(CH3COO)(P2W17O61)}2]16− (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated.
- Subjects
MAGNETIC properties; ERBIUM; ELECTROCHEMISTRY; MASS analysis (Spectrometry); PHOTOLUMINESCENCE
- Publication
Molecules, 2020, Vol 25, Issue 18, p4229
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules25184229