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- Title
Direct Synthesis of Thiocarbamoyl Fluorides and Trifluoromethylamines Through Fluorinative Desulfurization.
- Authors
Onida, Killian; Vanoye, Laurent; Tlili, Anis
- Abstract
Herein, a straightforward synthesis of thiocarbamoyl fluorides is reported starting from amines and carbon disulfide. The key to success is the fluorinative desulfurization of carbon disulfide with (diethylamino)sulfur trifluoride (DAST). The title compounds were obtained in moderate to very good isolated yields. Furthermore, we demonstrated also that thiocarbamoyl fluoride can be converted into their trifluoromethylamine analogues through simple treatment with silver fluoride.
- Subjects
FLUORIDES; CARBON disulfide; DESULFURIZATION; SULFUR
- Publication
European Journal of Organic Chemistry, 2019, Vol 2019, Issue 35, p6106
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201901113