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- Title
The Missing Binary Tungsten Iodide Archetype Cluster W<sub>4</sub>I<sub>10</sub>.
- Authors
Ströbele, Markus; Meyer, H.‐Jürgen
- Abstract
The tungsten iodide cluster W4I10 is obtained by thermal conversion of W4I13. The crystal structure of W4I10 was solved and refined by means of powder X-ray diffraction techniques. The structure is based on a tetrahedral tungsten cluster core, two face capping, five edge-bridging, and four apical iodido ligands of which two have bridging functionalities with adjacent clusters. Cluster chains in the structure are arranged following the motive of a kinked chain.
- Subjects
TUNGSTEN compounds synthesis; CRYSTAL structure; LIGANDS (Chemistry); TUNGSTEN compounds; CHAIN-propagating reactions; CRYSTALLOGRAPHY
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2016, Vol 642, Issue 24, p1409
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201600315