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- Title
3D electron diffraction analysis of a novel, mechanochemically synthesized supramolecular organic framework based on tetrakis‐4‐(4‐pyridyl)phenylmethane.
- Authors
Marchetti, Danilo; Pedrini, Alessandro; Massera, Chiara; Faye Diouf, Moussa Diame; Jandl, Christian; Steinfeld, Gunther; Gemmi, Mauro
- Abstract
Tetrakis‐4‐(4‐pyridyl)phenylmethane (TPPM) is a tetrahedral rigid molecule that crystallizes forming a dynamically responsive supramolecular organic framework (SOF). When exposed to different stimuli, this supramolecular network can reversibly switch from an empty to a filled solvated solid phase. This article describes a novel expanded form of a TPPM‐based SOF that has been mechanochemically synthesized and whose crystal structure has been determined by 3D electron diffraction analysis using a novel electron diffractometer.
- Subjects
TOLUENE; ORGANIC bases; TETRAHEDRAL molecules; CRYSTAL structure; ELECTRON diffraction; DIFFRACTOMETERS; COORDINATION polymers
- Publication
Acta Crystallographica Section B: Structural Science, Crystal Engineering & Materials, 2023, Vol 79, Issue 6, p432
- ISSN
2052-5192
- Publication type
Article
- DOI
10.1107/S2052520623007680