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- Title
Synthesis of the C<sub>18</sub>-Norditerpenoid Alkaloid Neofinaconitine: A Lesson in Convergent Synthesis Planning.
- Authors
Liu, Xiao‐Yu; Chen, David Y.‐K.
- Abstract
Hexacyclic framework: The total synthesis of the complex C18‐norditerpenoid alkaloid neofinaconitine has been achieved by a convergent approach. This remarkable synthesis featured two Diels–Alder cycloadditions and subsequent Mannich‐type N‐acyliminium and radical cyclizations to establish the unique hexacyclic core structure of the target molecule.
- Subjects
ALKALOIDS; MONKSHOODS; DELPHINIUM; MEMORIAL Sloan-Kettering Cancer Center; DIELS-Alder reaction
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 4, p924
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201309201